Academic qualification can only be issued by USNA and not everyone is told upfront that they are academically qualified. If you are told that in an official letter from the Admissions department then you would not be considered for NAPS. Being offered a candidate number does not mean that you are academically qualified or unqualified.
As many will tell you there is still the unknown about the entire admissions decision process on appointments. Please understand that if you are 3Q'd and even have nominations for multiple sources that you are not guaranteed an appointment. I have seen many over the years be disappointed and left wondering why because they were strong candidates.
The best advice you can be given is to present your best you that you can in your application, let those that you talk with know your heart's desire, and let the chips fall where they may. I would also add to get your application in as early as you are able to get it completed as it shows high motivation to the board. I understand that you are in college now so you need to wait on that first semester grades, but get everything else in as soon as you can.
Best of luck to you!