Initially, all 3Q + nom go on the NWL
Individuals who win an appointment from their MOC come off the NWL
Currently some individuals are not fully qualified, but would win that vacancy if they are - no appointment is awarded for that MOC until their status is resolved; however, some of those other candidates in that district who are fully qualified might be strong enough nationally to be appointed one of the top 150 spots.
Only candidates with a nomination from a MOC are eligible for the "top 150" which are officially called Qualified Alternates under congressional law.
Any fully qualified candidate regardless of nomination source is eligible for what is called an Additional Appointee which are the remaining vacancies to bring the initial class size up to the desired end strength -- usually around 1250. These candidates must be awarded appointments not to exceed 1 Service Connected nomination to 3 MOC. These spots often go to meet class composition goals to include those coming out of USMAPS. Don't expect to earn one of these appointments if your RC tells you that you are out of the running for you MOC and a NWL/Qualified Alternate/top 150 spots.
This is a roundabout way of saying yes, your nomination type matters, but not for the majority of candidates hoping to get in that do not win their MOC nomination slates. Also, don't think linearly. Just like the application process isn't linear (working multiple efforts simultaneously to train for the CFA, study for tests, apply for nominations, get medical done, etc), so is filling the class appointments from multiple nomination sources/types as fast as admissions legally is able.